PCL, Organophilic clay, Permeability, Fibers, Composites.
The improper disposal of polymers is responsible for its accumulation in nature, generating great environmental impacts, since degradation of polymers from non-renewable sources is quite slow. A viable alternative to minimize this problem is the total or partial repacement of synthetic polymers by biodegradable polymers. Polycaprolactone (PCL) is considered one of the most promising polymers for the production of biodegradable film packaging. The present study deals with the production, characterization and properties of films composed of biodegradable matrix (PCL) with organophilic clay (C20A), corn straw and sugarcane bagasse. The effect of the different types of fillers inserted in the polymeric matrix was investigated by analyzing film permeability, biodegradation, mechanical and thermal properties. The compounds containing 1.3 and 5% clay and fibers were processed in an internal laboratory mixer and the torque rheometry curves were analyzed. The compositions used were granulated and extruded as flat films. The results show that the addition of small amounts of organophilic clay and fibers did not increase the degradation of the PCL polymeric matrix during processing. Clay and fibers addition to the polymeric matrix decreased the permeability to oxygen gases and carbon dioxide of the films manufactured. As expected, the tensile strength and modulus of the films increase and their elongation at break decreased with filler (clay and vegetable fibers) addition. DSC data show that the melting and crystallization temperatures of the composite films did not change with the addition of fibrous and particulate fillers.